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Reference




Phosphorus
Chemical Properties & Compounds



Symbol Atomic Number Atomic Weight Melting Point Boiling Point Phase Density Classification
P 15 30.973762 44.2 °C 277 °C Solid 1.82 g/cm3 Non-Metal Toxic Element


15 siliconphosphorussulfur
N

P

As
General
Name, symbol, number phosphorus, P, 15
Chemical series nonmetals
Group, period, block 153, p
Appearance waxy white/ red/
black/ colorless
Standard atomic weight 30.973762(2) g·mol−1
Electron configuration [Ne] 3s2 3p3
Electrons per shell 2, 8, 5
Density (near r.t.) (white) 1.823 g·cm−3
Density (near r.t.) (red) 2.34 g·cm−3
Density (near r.t.) (black) 2.69 g·cm−3
Melting point (white) 317.3 K
(44.2 °C, 111.6 °F)
Boiling point 550 K
(277 °C, 531 °F)
Heat of fusion (white) 0.66 kJ·mol−1
Heat of vaporization 12.4 kJ·mol−1
Heat capacity (25 °C) (white)
23.824 J·mol−1·K−1
Vapor pressure (white)
P/Pa 1 10 100 1 k 10 k 100 k
at T/K 279 307 342 388 453 549
Vapor pressure (red)
P/Pa 1 10 100 1 k 10 k 100 k
at T/K 455 489 529 576 635 704
Oxidation states ±3, 5, 4
(mildly acidic oxide)
Electronegativity 2.19 (Pauling scale)
Ionization energies
(more)
1st: 1011.8 kJ·mol−1
2nd: 1907 kJ·mol−1
3rd: 2914.1 kJ·mol−1
Atomic radius 100 pm
Atomic radius (calc.) 98 pm
Covalent radius 106 pm
Van der Waals radius 180 pm
Miscellaneous
Magnetic ordering no data
Thermal conductivity (300 K) (white)
0.236 W·m−1·K−1
Bulk modulus 11 GPa
CAS registry number 7723-14-0
Selected isotopes
Main article: Isotopes of phosphorus
iso NA half-life DM DE (MeV) DP
31P 100% P is stable with 16 neutrons
32P syn 14.28 d β- 1.709 32S
33P syn 25.3 d β- 0.249 33S
References
Phosphorus Compounds

Source: Wikipedia article Phosphorus


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